Personally I like to place my business address at the bottom of the page or the footer. To do this go to the floating bar and click on the button, 'Switch Between Header and Footer.' This will open a dotted box at the bottom of the document. You can type your office address here or anything you see fit for your letterhead. Again you can format the text by choosing the font, font size, color, align the text, etc.
Click on the the template. At the bottom right of the dialogue you'll see two options: 'Document' and 'Template'. If you want to use the letterhead to send as a document or letter, choose 'Document.' If you want to edit the template, choose 'Template.' When you choose 'Document,' it gets saved as an MS Word document.