That's how to create a business letterhead in Word. Now, how do you monetize this new_found knowledge? Offer to your community a letterhead printing service. You can offer to design a logo and print the letterhead. Don't know how to design? Outsource it and then mark it up. Then go to a printing press, get a quotation to print letterheads and then mark it up. But don't mark it up too much. The point is to get as many clients as possible even with a small profits. Several small profits will always add up to big profits.
You also have several templates to choose from with Open Office software, but Microsoft Word provides a wider selection. However, if you do find a template that seems good enough and you'd like to customize it, go to Wordlabel.com to download the file. To open it, right click Open With and then select the software. You can then modify it however you want.